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Chiral Reagents for Asymmetric Synthesis - Google Books
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Web(-)-Diisopinocampheyl borane C20H34B CID 12482041 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, … Web1-Bromo-2-chloroethene C s. 1,2-Dichloro-1,2-difluoroethane C 2 H 2 F 2 Cl 2 C i. 1,2-Dichlorobenzene – C 2v. 1,3-Dichlorobenzene – C 2v. 1,4-Dichlorobenzene D 2h. Ammonia C 3V. Analysis of Atomic Displacements in Water. Aniline Yellow. Anomeric Effect for different substituents. Web1 jan. 1992 · We found that the imine 2a was readily reduced by a chiral borane la (5 mol eq.) at room temperature in the presence of MgBr2*OEt2 (1.2 mol eq.) in THP to give the amine 3a in 91% yield with 73%ee. Without MgBr2*OEt2, the reaction did not take place. The use of other additives such as ZnCl2, TiCU, ZrCU, CeCIs, and MesSiOTf for this … grade 5 math division